Efficient Blue Photo‐ and Electroluminescence from CF₃‐Decorated Cu(I) Complexes

Abstract

Luminescent organometallic complexes of earth‐abundant copper(I) have long been studied in organic light‐emitting diodes (OLED). Particularly, Cu(I)‐based carbene‐metal‐amide (CMA) complexes have recently emerged as promising organometallic emitters. However, blue‐emitting Cu(I) CMA complexes have been rarely reported. Here we constructed two blue‐emitting Cu(I) CMA emitters, MAC*‐Cu‐CF3Cz and MAC*‐Cu‐2CF3Cz, by introducing one or two CF3‐ substitutes into carbazole ligands. Both complexes exhibited high thermal stability and blue emission colors. Moreover, two complexes exhibited different emission origins rooting from different donor ligands: a distinct thermally activated delayed fluorescence (TADF) from ligand‐to‐ligand charge transfer excited states for MAC*‐Cu‐CF3Cz or a dominant phosphorescence nature from local triplet excited state of the carbazole ligand for MAC*‐Cu‐2CF3Cz. Inspiringly, MAC*‐Cu‐CF3Cz had high photoluminescence quantum yields of up to 94% and short emission lifetimes of down to 1.2 μs in doped films, accompanied by relatively high radiative rates in the 105 s−1 order. The resultant vacuum‐deposited OLEDs based on MAC*‐Cu‐CF3Cz delivered pure‐blue electroluminescence at 462 nm together with a high external quantum efficiency of 13.0%.