Efficient approach to thiazolidinones via a one-pot three-component reaction involving 2-amino-1-phenylethanone hydrochloride, aldehyde and mercaptoacetic acid

Design of a new multi-functional catalytic system Ni/SO3H@zeolite-Y for three-component synthesis ofN-benzo-imidazo- or -thiazole-1,3-thiazolidinones

“…The classical synthesis reported can be either a one-pot or a twostep process through condensation of amines and aromatic aldehydes, and thioglycolic acid. Although various heterogeneous and homogenous catalysts have been applied for the substituted 1,3-thiazolidin-4-ones, [24][25][26][27][28][29][30][31][32][33][34][35][36][37][38] synthesis of new thiazolidine heterocycles and exploration for greener and cleaner synthetic strategies still remains as an active research.…”

Fe3O4@Zeolite‐Y Functionalized with N‐Methylimidazolium Ionic Liquid: Design and Performance as a New Recyclable and Magnetically Nanocatalyst in the Three‐Component Synthesis of N‐Heterocyclic‐1,3‐thiazolidinones

“…[a] DIPEA (3 equiv) Toluene, reflux 180-240 (65-85) [30] 5 CoFe 2 O 4 @SiO 2 /Pr-NH 2 (0.7 mol %) PhCH 3 , reflux 120-480 (75-85) [31] 6 Silica gel (0.5 g) THF, RT 240-420 (77-96) [32] 7 TCH/Pd@SBA-15 (3 wt%) acetone-H 2 O 15-24 (86-98) [33] 8 Fe 3 O 4 /SiO 2 /Salen/Mn/IL (0.8 mg) Solvent-free, RT 30 (88-94) [34] 9 HClO 4 À SiO 2 (47 wt%) PhCH 3 , 100 °C 180-360 (70-88) [45] 10 Ni@zeolite-Y (10 wt%) EtOH, RT 25-35 (80-95) [12] 11 Fe 3 O 4 @SiO 2 /APTPOSS (8 wt%) Solvent-free, 60 °C 30 (90-94) [46] 12 1-MeIm IL@ZY-Fe 3 O 4 (5 mg) EtOH, RT 15-21 87-96 (This work)…”

“…Finally, after intermolecular nucleophilic attack and the removal of another H 2 O molecule, the N-heterocyclic-1,3thiazolidin-4-one compounds (4 a-l) can be obtained. [28a, 30,33] The recyclability process of the catalyst (1-MeIm IL@ZY-Fe 3 O 4 ) was tested for the model reaction. The 1-MeIm IL@ZY-Fe 3 O 4 was recovered from the reaction mixture at the end of each run by using an external magnet, and then washed with ethyl acetate and dried at 80 °C.…”

Pd Doped on TCH@SBA-15 Nanocomposites: Fabrication and Application as a New Organometallic Catalyst in the Three-Component Synthesis of N-Benzo-imidazo- or -thiazole-1,3-thiazolidinones

“…step process of an amine with aromatic aldehydes and thioglycolic acid, under traditional hard conditions, or with the use of heterogeneous and homogenous catalysts (Srivastava et al, 2001;Kumar et al, 2013;Thakare et al, 2014;Jadhav et al, 2015;Chate et al, 2016;Harale et al, 2016;Pang et al, 2016;Thakare et al, 2016;Kalhor et al, 2017;Kalhor et al, 2018;Kalhor and Banibairami, 2020). However, despite reports of good progress in the synthesis of these valuable compounds, there are still some limitations to these methods and research and development to achieve new, more efficient, and greener synthetic strategies is useful and in demand.…”