2006
DOI: 10.1016/j.solmat.2006.06.002
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Efficiency limits for single-junction and tandem solar cells

Abstract: Basic limitations of single-junction and tandem p-n and p-in diodes are established from thermodynamical considerations on radiative recombination and semi-empirical considerations on the classical diode equations. These limits are compared to actual values of short-circuit current, open-circuit voltage, fill factor and efficiency for amorphous (a-Si:H) and microcrystalline (mc-Si:H) silicon solar cells. For single-junction cells, major efficiency gains should be achievable by increasing the short-circuit curr… Show more

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Cited by 336 publications
(238 citation statements)
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References 10 publications
(7 reference statements)
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“…[6][7][8][9][10] The top sub-cell in a silicon-based tandem should have a band gap between 1.6 and 1.9 eV. 11 However, very few materials exhibit high open-circuit voltages (V OC ) within this band gap range. Recently, the methylammonium-lead-halide perovskite has demonstrated a rapid efficiency increase [12][13][14][15][16] with a V OC of 1.15 V. 17 The methylammonium-lead-halide perovskite has a tunable band gap, ranging from 1.6 to 2.3 eV depending on halide composition, 18 though not all compositions are currently stable under illumination.…”
mentioning
confidence: 99%
“…[6][7][8][9][10] The top sub-cell in a silicon-based tandem should have a band gap between 1.6 and 1.9 eV. 11 However, very few materials exhibit high open-circuit voltages (V OC ) within this band gap range. Recently, the methylammonium-lead-halide perovskite has demonstrated a rapid efficiency increase [12][13][14][15][16] with a V OC of 1.15 V. 17 The methylammonium-lead-halide perovskite has a tunable band gap, ranging from 1.6 to 2.3 eV depending on halide composition, 18 though not all compositions are currently stable under illumination.…”
mentioning
confidence: 99%
“…We have also used a graded heterojunctions in both sides of intrinsic layer in order to ensure the band continuity at interfaces. For Si-based bottom cell, the top cell bandgap should be between 1.7 and 1.8 eV in order to achieve the current matching [1]. For this reason, we have varied the indium composition from 45% to 55%.…”
Section: Resultsmentioning
confidence: 99%
“…However, it is hard to find a matched-bandgap material with silicon (1.7-1.8 eV) [1]. The maximum power conversion efficiency (PCE) for a tandem solar cell is 31.6% for GaInP/GaAs tandem cell [2].…”
Section: Introductionmentioning
confidence: 99%
“…The approach is to fabricate p-n, p-i-n or any other diode structure with different band gap semiconductors and connect them to enhance the photovoltaic conversion. The fundamental limit of the performance of tandem structures has been studied by Meillaud et al (Meillaud et al, 2006). The radiative efficiency limit for a single junction silicon cell is 30%.…”
Section: Multilayer Tandem Solar Cellsmentioning
confidence: 99%