Conventional coupled-channels analyses, that take account of only the collective excitations of the colliding nuclei, have failed to reproduce the different behavior of the experimental quasi-elastic barrier distributions for the 20 Ne + 90,92 Zr systems. To clarify the origins of this difference, we investigate the effect of non-collective excitations of the Zr isotopes. Describing these excitations in a random-matrix model, we explicitly take them into account in our coupled-channels calculations. The non-collective excitations are capable of reproducing the observed smearing of the peak structure in the barrier distribution for 20 Ne + 92 Zr, while not significantly altering the structure observed in the 20 Ne + 90 Zr system. The difference is essentially related to the closed neutron shell in 90 Zr.