1990
DOI: 10.1002/pc.750110102
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Effects of water sorption on the physical properties of PET, PBT, and their long fibers composites

Abstract: The behavior of poly(ethylene terephthalate) (PET) and poly(butylene terephthalate) (PBT) on water aging has been studied above and below the glass transition temperature (Tg). The aging process is caused by: degradation of the matrix and an increase in crystallinity above Tg, and microcavitation at the amorphous/crystalline interface below Tg. Such behavior well explains the deviation of the sorption kinetics from the Fickian model. The apparent water diffusion coefficients and the transport activation energi… Show more

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Cited by 44 publications
(40 citation statements)
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“…Although Fickian behaviour has been observed for most of the polymers, some exceptions in some conditions have also been reported . For example, at elevated temperatures where the thermal ageing, oxidation, leaching and formation of crystalline are important, there is more deviation from Fick's law .…”
Section: Effects Of Thermal and Hygrothermal Ageing On Tensile Behaviourmentioning
confidence: 99%
See 2 more Smart Citations
“…Although Fickian behaviour has been observed for most of the polymers, some exceptions in some conditions have also been reported . For example, at elevated temperatures where the thermal ageing, oxidation, leaching and formation of crystalline are important, there is more deviation from Fick's law .…”
Section: Effects Of Thermal and Hygrothermal Ageing On Tensile Behaviourmentioning
confidence: 99%
“…Although Fickian behaviour has been observed for most of the polymers, some exceptions in some conditions have also been reported . For example, at elevated temperatures where the thermal ageing, oxidation, leaching and formation of crystalline are important, there is more deviation from Fick's law . In the study of Bastioli et al on PBT and PET thermoplastic composites, the maximum water absorbed increased as ageing temperature increased, probably because of the modification of crystalline‐amorphous interface during the absorption process.…”
Section: Effects Of Thermal and Hygrothermal Ageing On Tensile Behaviourmentioning
confidence: 99%
See 1 more Smart Citation
“…DSC was also used to analyze neat PBT fibers (drawn and extracted), and the SPCs after hot compaction, and identify their respective crystallinities, with enthalpy of melting of 100% crystalline PBT taken as 143.4 J=g [48] , and crystallinity of each examined material calculated from their enthalpies of melting with respect to that of fully crystalline PBT.…”
Section: Thermal Characterization Using Differential Scanning Calorimmentioning
confidence: 99%
“…While there is no concern about the time dependence of the mechanical properties of commonly used metal wires in the oral environment, both time and environment affect significantly the performance of FRC appliances [13][14][15][16]. These effects in long-fibre thermoplastic composites are assumed to be mostly due to the hydrolytic deterioration of the fibres, matrix and interface [17] as well as the viscoelastic character of the matrix [18].…”
Section: Introductionmentioning
confidence: 99%