The thermal desorption spectra between 400 K and 1100 K and the internal friction spectra between 80 K and 423 K were studied for a-Si(H). The thermal desorption of hydrogen was observed around 650 K (TDH 650K ) and around 900 K (TDH 900K,L and TDH 900K,H ). Both TDH 900K,L and TDH 900K,H with the activation energy of 1.6 eV were attributed to the desorption of bonded hydrogen. TDH 650K was not a diffusion controlled process with the activation energy of 1.0 eV, where one part of TDH 650K was attributed to the desorption of isolated hydrogen molecules. The hydrogen-induced internal friction, H-Q -1 a-Si(H) , was observed between 80 K and 423 K. Hydrogen responsible for H-Q -1 a-Si(H)showed the thermal desorption around 650 K (TDH 650K ), indicating that isolated hydrogen molecules in the amorphous structure may be responsible for H-Q -1 a-Si(H) . Light soaking caused changes in H-Q -1 a-Si(H) in the temperature ranges between 80 K and 200 K and between 200 K and 300 K, indicating that light soaking modified the local amorphous structures responsible for these changes in Q -1 a-Si(H) .