“…Unsaturated flow is a fundamental aspect of groundwater flow and solute transport (e.g., Barry, Barry, & Parlange, 1996;Geng et al, 2017Geng et al, , 2020Kong et al, 2015;Luo et al, 2018;Luo, Kong, Yao, et al, 2023;Luo, Kong, Yu, et al, 2023;Parlange & Brutsaert, 1987). Šimůnek et al (2006) accounted for unsaturated flow effects in a reactive transport model HP1.…”