“…There is a general agreement that the overall resistance of the PTCR ceramics was dependent on the resistance of the grain boundary regions, the value being affected by interaction with oxygen and changes to the density of acceptor states during processing [16]. At reoxidation stage, oxygen vacancies were lost and the Na-ions at the grain boundaries formed acceptor states, which led to the increase of room temperature resistivity.…”
“…There is a general agreement that the overall resistance of the PTCR ceramics was dependent on the resistance of the grain boundary regions, the value being affected by interaction with oxygen and changes to the density of acceptor states during processing [16]. At reoxidation stage, oxygen vacancies were lost and the Na-ions at the grain boundaries formed acceptor states, which led to the increase of room temperature resistivity.…”
“…La 3+ , Sb 3+ ) substitution on Ba 2+ site, or pentavalent ion (e.g. Nb 5+ , Ta 5+ ) substitution on Ti 4+ sites of the perovskite ABO 3 lattice [7]. Fe doped BaTiO 3 solid solutions are found to exhibit multiferroic properties, however ferroelectric properties of Fe-doped BT are not as pronounced as those of pure BT [8].…”
ceramics were fabricated by conventional mixed oxide route to develop inorganic dielectric materials suitable for use as an insulator with high dielectric constant and low energy loss for capacitor applications. The structural phase transition, ferroelectric, dielectric and energy storage properties of BCT, BZT ceramic capacitors were investigated. Room temperature X-ray diffraction (XRD) patterns revealed prominent peaks corresponding to tetragonal perovskite crystal structure for both BCT, BZT solid solutions. Slim ferroelectric hysteresis (P-E) loops were observed for BCT, BZT solid solutions. Temperature dependent dielectric property measurements of BCT, BZT solid solutions have shown a high dielectric constant and low dielectric loss. Room temperature (300K) breakdown field strength and energy densities were obtained from the integral area of P-E loops. For the BCT ceramics, the largest recoverable energy (unreleased energy) density is 1.41 J/cm 3 with dielectric breakdown strength as high as 150 kV/cm. For the BZT ceramics, the largest recoverable energy (unreleased energy) density is 0.71 J/cm 3 with dielectric breakdown strength as high as 150 kV/cm. Bulk BCT, BZT ceramics have shown interesting energy densities; these might be the strong candidate materials for capacitor applications.
“…A shift of the phase transition temperature toward low or high temperatures was achieved by partial substitution of Ba 2þ ions by Sr 2þ or Pb 2þ , respectively [2,3]. However, lead-containing materials are highly toxic [4].…”
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.