A compression wave in a canal is an unsteady motion characterised by a rapid rise of water surface elevation, resulting in an unsteady turbulent flow. In the present study, the hydrodynamics of unsteady compression wave flows were experimentally investigated using an array of two profiling velocimeters, sampled simultaneously.The two-dimensional cross-correlation data in the y-z plane, formed by the two sampling profiles, showed the existence of large scale coherent structures underneath the free-surface, resembling the shape of hairpin vortex. The length scales tended to increase during and after the compression wave passage compared to those during the initially steady flows. Both strain rate and vorticity showed larger values at lower water column near the channel bed, and during the rapid deceleration phase associated with immediate wave passage. The propagation of the compression wave was a dynamically-active process, with large scale transient coherent motions, vortical structures and intensive turbulent mixing occurring underneath.