Effects of the Surface Structure on the Water Transport Behavior in PEMFC Carbon Fiber Papers

Abstract

In this paper, three kinds of carbon fiber papers (CFPs), including pure CFP, poly­(tetrafluoroethylene) (PTFE)-treated CFP (PTFE-CFP), and microporous layer (MPL)-coated CFP (MPL-CFP), were used to investigate the effects of the surface structure on the water transport behavior in CFPs. Compared to pure CFP, applying PTFE on the CFP increases the breakthrough pressure by 0.2 times, while it decreases the water flow rate at initial penetration by 0.06 times, owing to the strong hydrophobicity of PTFE-CFP. The pore diameter of MPL-CFP reduces sharply after coating the MPL, which leads to increasing breakthrough pressure by 0.6 times. The Young–Laplace equation is applied to study the relationship between the structure (wettability and pore-size distribution) of CFPs and the water transport behavior (breakthrough pressure), and the results show that in addition to wettability and pore size, the pore-size gradient also plays a crucial role in water transport.

Control Mechanism of a Modified Buffer Layer on Interfacial Mass Transfer Efficiency for a Proton Exchange Membrane Fuel Cell at Varying Humidity

“…Besides, small pores can be observed on the surface of the carbonaceous filler . This hierarchical pore structure in carbon paper is conducive to create a pathway for gas transfer and water removal. , …”

“…28 This hierarchical pore structure in carbon paper is conducive to create a pathway for gas transfer and water removal. 29,30 The commercial GDL without any modification is termed Com-GDL. The MPL coated on Com-GDL is shown in Figure 1b.…”