AlGaN-based deep-ultraviolet light-emitting diodes (DUV-LEDs), which emit at around 280 nm, have attracted a great deal of interest due to their wide range of potential applications such as water purification, sterilization, biological disinfections, and medical therapy. [1][2][3] Nevertheless, the efficiency of DUV-LEDs is much lower than that of the InGaN-based visible LEDs, which has become a bottleneck limiting their widespread commercial applications. The strong built-in polarization electric field and insufficient carrier confinement in the multiple-quantum-well (MQW) active region are two important issues limiting the output performance of the DUV-LEDs. To improve the carrier confinement, a simple method is to increase Al composition of the barrier layer. However, it brings some drawbacks including a more serious lattice mismatch between wells and barriers, which will produce the dislocations and severe quantum-confined Stark effects (QCSEs). The strengthened polarization electric field will further reduce the electronhole wave function overlap, and deteriorate the radiative recombination rate of the MQWs. In addition, the strong confining potential of quantum wells (QWs) will increase the ratio of Auger recombination. [4,5] The DUV-LEDs generally possess shallower wells to lower the lattice mismatch between the QWs and the quantum barriers (QBs), however, which will result in poor carrier confinement. Therefore, there is a trade-off between the carrier confinement and the overlap of the wave functions. [6] In particular, the insufficient carrier confinement in the MQWs will result in large amount of electrons concentrated in the last QW (LQW) close to the p-type electron blocking layer (p-EBL), and the electrons would be easily leaked into the p-type region to decrease the emission efficiency, especially at high current density injection. [7][8][9][10] To suppress electron leakage, many studies have focused on the p-EBL, [11][12][13][14] however, the p-EBL might also introduce a higher barrier in the valence band, hindering the injection efficiency of the holes. Recently, great efforts have been made to deal with the issues mentioned earlier. [15][16][17][18][19][20][21] The tailored Si-doping in the QBs is used by Zhu et al. to enhance the confinement of electrons in the QWs. [8] Li et al. designed triangular QBs to suppress the electron overflow and decrease the electrostatic field in the active region. [15] Lin et al. show a quaternary AlInGaN MQW design to reduce the polarization effect and suppress the electron leakage. [16] The compositional modulation schemes for the Al x Ga 1-x N MQWs have proposed by Kojima et al. to reduce the separation of the electron-hole wave functions. [17] Graded Al-composition in the QW layers shown by Yu et al. showed an improvement of the electron-hole wave function overlap due to the screening of the QCSE. [18]