Abstract:An alternative indium-free material for transparent conducting oxides of fluorine-doped tin oxide [FTO] thin films deposited on polyethylene terephthalate [PET] was prepared by electron cyclotron resonance - metal organic chemical vapor deposition [ECR-MOCVD]. One of the essential issues regarding metal oxide film deposition is the sheet resistance uniformity of the film. Variations in process parameters, in this case, working and bubbler pressures of ECR-MOCVD, can lead to a change in resistance uniformity. B… Show more
“…15 The maps suggest the Cr-nd FTO heater shows the most uniform value (14.65%), followed by NiCr-nd FTO (19.2%), bare FTO (19.7%), and Ni-nd FTO (30%). The thermal uniformity of our FTO-based heaters seemed much better than that developed with a patterned wire, 20 a heater type commonly used to remove mist in conventional car windows today.…”
Facile production and novel transparent heaters consisting of fluorine-doped tin oxide (SnO2:F or FTO) thin films covered with three different scattered metal nanodots (Cr-nd, NiCr-nd and Ni-nd) prepared by plasma-enhanced sputtering system and electron cyclotron resonance-metal organic chemical vapor deposition are investigated. The heaters exhibit excellent optical transmittances of over 85% and superior saturated temperatures of more than 80 °C when a relatively low 12 V DC is supplied. The scattered metal nanodots FTO heaters successfully improve the specific power of bare FTO heater by 21, 15, and 12% for NiCr-nd FTO, Cr-nd FTO, and Ni-nd FTO, respectively. These results reveal that the FTO transparent heaters with scattered metal nanodots are the suitable heating materials that can be applied for various functional devices.
“…15 The maps suggest the Cr-nd FTO heater shows the most uniform value (14.65%), followed by NiCr-nd FTO (19.2%), bare FTO (19.7%), and Ni-nd FTO (30%). The thermal uniformity of our FTO-based heaters seemed much better than that developed with a patterned wire, 20 a heater type commonly used to remove mist in conventional car windows today.…”
Facile production and novel transparent heaters consisting of fluorine-doped tin oxide (SnO2:F or FTO) thin films covered with three different scattered metal nanodots (Cr-nd, NiCr-nd and Ni-nd) prepared by plasma-enhanced sputtering system and electron cyclotron resonance-metal organic chemical vapor deposition are investigated. The heaters exhibit excellent optical transmittances of over 85% and superior saturated temperatures of more than 80 °C when a relatively low 12 V DC is supplied. The scattered metal nanodots FTO heaters successfully improve the specific power of bare FTO heater by 21, 15, and 12% for NiCr-nd FTO, Cr-nd FTO, and Ni-nd FTO, respectively. These results reveal that the FTO transparent heaters with scattered metal nanodots are the suitable heating materials that can be applied for various functional devices.
“…Moreover, the FOM obviously was reduced to a value lower than unity for the cosputtered ITO-ZnO film's contact n-GaN epilayer. This value is calculated according to the following expression which takes into consideration both the specific contact resistance, ρc, and the average optical transmittance, Tave [19,20]: The higher the FOM of the Ti/ITO-ZnO system obtained, the better the quality of the transparent electrode contacted to the n-GaN epilayer. Table 2 gives the FOM of the Ti/ITO-ZnO systems as a function of the thickness of the Ti interlayer.…”
Section: Resultsmentioning
confidence: 99%
“…2016, 6, 60 6 of 9 n-GaN epilayer. This value is calculated according to the following expression which takes into consideration both the specific contact resistance, ρc, and the average optical transmittance, Tave [19,20]: Table 2. Specific contact resistance, optical average transmittance, and FOM of the Ti/ITO-ZnO systems as a function of the thickness of the Ti interlayer (the specific contact resistance of the TI/Al contact to the n-GaN epilayer also is given for comparison).…”
Section: Resultsmentioning
confidence: 99%
“…Herein, we proposed the figure of merit (FOM), Φ, to quantitatively determine the performance of these transparent electrodes' ohmic contact to the n-GaN epilayer. This value is calculated according to the following expression which takes into consideration both the specific contact resistance, ρ c , and the average optical transmittance, T ave [19,20]:…”
Transparent indium tin oxide (ITO) and cosputtered ITO-zinc oxide (ZnO) films' contacts to an n-GaN epilayer were investigated. Both of these electrodes' contact to the n-GaN epilayer showed Schottky behavior, although the contact resistance of the ITO-ZnO/n-GaN system was lower than that of the ITO/n-GaN system. By placing a thin Ti interlayer between the ITO-ZnO/n-GaN interface, nonalloyed ohmic contact was achieved. The inset Ti interlayer was both beneficial both for enhancing the outdiffusion of the nitrogen atoms at the surface of the n-GaN and suppressing the indiffusion of oxygen atoms from the surface of the ITO-ZnO to n-GaN. The figure-of-merit (FOM), evaluated from the specific contact resistance and optical property of the Ti/ITO-ZnO system's contact to the n-GaN epilayer, was optimized further at an adequate thickness of the Ti interlayer.
“…Other factors arise from the challenges of depositing thin films over large area (∼ m 2 ) substrates in TFPV module manufacturing. These include film thickness variation over large area substrates [8], variation of contact sheet resistance [9], composition variations in chalcogenide cells [10]. These manufacturing challenges not only reduce the module efficiency, but also lead to performance variation at the module level, causing reduced process yield.…”
The gap between cell and module efficiency is a major challenge for all photovoltaic (PV) technologies. For monolithic thin film PV modules, a significant fraction of this gap has been attributed to parasitic shunts, and other defects, distributed across the module. In this paper, we show that it is possible to contain or isolate these shunt defects, using the state of the art laser scribing processes, after the fabrication of the series connected module is finished. We discuss three possible alternatives, and quantify the performance gains for each technique. We demonstrate that using these techniques, it is possible to recover up to 50% of the power lost to parasitic shunts, which results in 1-2% (absolute) increase in module efficiencies for typical thin film PV technologies.
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