Electro-coagulation analytical technique has been used for the removal of malachite green -a dyestuff used as antimicrobial in aquaculture. Effects of parameters such as current density, pH, dye initial concentration, interelectrode separation and amount of electrolyte on the dye color-removal have been investigated using Al and Fe as scarifying anodes. It was observed that whereas increase in dye initial concentration or inter-electrode separation, the rate of color removal continuously falls, however, on raising of electrolyte concentration, color removal rate enhances up to a definite electrolyte level, beyond that there was no further improvement in the color removal. Further, for achieving maximum color removal of malachite green aqueous solution optimum current density (76.5A/m 2 ) and pH (8.0) of solution, is required. Complete color removal of 100mg/L malachite green aqueous solution could be achieved in 30min using electrolyte (NaCl) concentration 0.4g/L, inter-electrode distance: 1cm and optimum pH and current density. Performance of Al and Fe as sacrificial electrodes, in terms of their color removal efficiency, was almost similar except in their response to inter-electrode separation, as variable, where in case of Fe as anode, color removal rate declined more rapidly. The outcome of the present research work may be useful for an effective large scale treatment of industrial effluents contaminated with malachite green dye.
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