Effects of nonaromatic through‐bond conjugation and through‐space conjugation on the photoluminescence of nontraditional luminogens
Xiaomi Zhang,
Yunhao Bai,
Junwen Deng
et al.
Abstract:Photoluminescence (PL) mechanisms of nontraditional luminogens (NTLs) have attracted great interest, and they are generally explained with intra/intermolecular through‐space conjugation (TSC) of nonconventional chromophores. Here a new concept of nonaromatic through‐bond conjugation (TBC) is proposed and it is proved that it plays an important role in the PL of NTLs. The PL behaviors of the three respective isomers of cyclohexanedione and gemdimethyl‐1,3‐cyclohexanedione were studied and correlated with their … Show more
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