Effects of Nano‐SiC on Silane Grafting and Curing of Polyolefin Elastomer: Mixing Order, Physical, and Mechanical Properties

Abstract

The objective of this article was preparation of curable silane‐grafted poly(ethylene‐1‐butene) nanocomposite. The poly(ethylene‐1‐butene) was a polyolefin elastomer with random high comonomer content. Two preparation methods were investigated. The method of preparing nanocomposites significantly affected the mechanical properties of the resulted nanocomposites. So that, with the same formulation and different preparation methods, silane grafting with the first was 94% (PVDS3), while with the second was 33% (PS3VD). It was shown that the tensile strength of the cured nanocomposite prepared with the method 1 (PVDS3) increased four times higher than the pure resin. The effects of different factors such as the amount of silane and also the amount of silicon carbide on the physical, mechanical, and thermal properties of the cured and uncured nanocomposites were investigated. The rate of curing was depended on the silicon carbide concentration and 5 phr (part per hundred resin), and nano‐SiC was a concentration where the tensile properties were optimum. Thermal stability and the impermeability of the cured samples improved in the presence of nano‐silicon carbide. J. VINYL ADDIT. TECHNOL., 26:244–252, 2020. © 2019 Society of Plastics Engineers

An overview of boron nitride based polymer nanocomposites

“…The polymer composites using inorganic nanomaterials as fillers have attracted much attention owing to their distinctive properties and various potential applications in the construction, automotive, aerospace and electronics industries. [5][6][7][8] In order to enhance the functionality and performance of a polymer nanocomposites, thermally conductive inorganic fillers like silicon carbide, [9] aluminum nitride, [10] aluminum oxide, [11] boron nitride, [12] etc., and metal oxide fillers such as SiO 2 and TiO 2 have been explored. [13,14] Noble metals such as gold and silver can also be used, however with limited applications due its expensive nature.…”