1999
DOI: 10.1002/(sici)1097-4628(19991017)74:3<601::aid-app14>3.0.co;2-k
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Effects of mechanical deformations on the structurization and electric conductivity of electric conducting polymer composites

Abstract: Structural changes proceeding in composites under the effect of various mechanical deformations (stretching, compression, shear, etc.) affect the structure of an electrical conducting system. Mechanical stresses, induced by deformation of composite materials during deformation, affect both the molecular and supermolecular structure of polymers. As a consequence, they also affect a substructure bound to it and composed of filler particles. It is evident that in the case of conducting polymer composites, mechan… Show more

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Cited by 84 publications
(54 citation statements)
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References 13 publications
(22 reference statements)
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“…Irreversible change in the electrical resistance at deformation by stretch or pressure has been found in the case of micro-size particles of good conductors as well as low structure carbon black (LSCB) [2][3][4].…”
Section: Introductionsupporting
confidence: 72%
See 1 more Smart Citation
“…Irreversible change in the electrical resistance at deformation by stretch or pressure has been found in the case of micro-size particles of good conductors as well as low structure carbon black (LSCB) [2][3][4].…”
Section: Introductionsupporting
confidence: 72%
“…The electrical resistance of PCFC is sensitive to various external force parameters [1][2][3][4][5][6], such as pressure, deformation, gaseous environment and temperature. The above-mentioned polymer composites promise to replace conventional rigid inorganic sensors in certain applications due to their flexibility and ease of processing.…”
Section: Introductionmentioning
confidence: 99%
“…[13][14][15][16][17][18][19][20][21][22][23][24][25][26][27] Many experimental works have been reported concerning the effect of mechanical stress on G ͑Refs. 9, 19, and 28-39͒ and the ac-impedance of composites, [38][39][40][41][42] but the systematic theoretical investigation of the dependence of G with the external applied stress has been initiated in a few relevant works in recent years. [13][14][15][16][17]20,21,24 The main experimental features commonly observed in pressure sensors based on elastomer composites are high sensitivity at low applied stress, currently with exponential rise of G as function of the applied pressure, followed by saturation.…”
Section: Introductionmentioning
confidence: 99%
“…The filler concentration at which the electrical conductivity of a composite would drastically change due to a tensile strain corresponds to the upper bound of the percolation region (transition from Stage III to Stage IV) and is called the critical (target) concentration. This strain-induced change in the electrical conductivity is referred to as tensoresistivity and is represented by the gauge factor, which is defined as the relative change in a specimen's electrical resistance per unit strain, e, as [15]:…”
Section: Conductive Nanocompositesmentioning
confidence: 99%