Scanning tunneling spectroscopy was performed on c-axis Y1−xCaxBa2Cu3O 7−δ thin films for x = 0, 0.05, 0.15 and 0.20 at 4.2K. The measured spectra show main-gap, sub-gap and satellite features which scale similarly in energy versus Ca-doping, suggesting that they are associated with a single pairing energy. The data is analyzed with a multiband tunneling model which attributes the sub-gap features to the chain band and the satellite and main-gap features to the plane band for d x 2 −y 2 + s pairing symmetry. These results suggest that the superconductivity in Y1−xCaxBa2Cu3O 7−δ involves multiple bands.Common to all the copper-oxide based hightemperature superconducting compounds are the CuO 2 planes. The CuO 2 planes are believed to be responsible for the wealth of phenomena observed in these materials [1], particularly the formation of Cooper pairs withis peculiar among the cuprates in that it also has quasi-onedimensional, metallic CuO chains, which may contain finite superfluid density below the superconducting critical temperature (T c ) as suggested by various bulk probes [3,4,5]. Since long-range order cannot be easily sustained in one-dimension, the apparent presence of superfluid density in the chains suggests that the plane and chain bands are electronically coupled. Such coupling would imply that the superconductivity in YBCO is essentially multiband in nature [6,7,8,9,10,11], and could conceivably affect its pairing symmetry. In fact, recent pair-tunneling experiments [12,13] have revealed a twofold, d x 2 −y 2 + s pairing symmetry [14,15] in optimallydoped YBCO, with the d-wave node lines rotated away from the chain axis.At present it is not yet clear from these pair-tunneling experiments whether the observed d + s pairing symmetry is intrinsic to the planes [16], or it is an effect of coupling between the plane and chain bands [6,7,8,9,10]. Quasiparticle tunneling spectroscopy could help to elucidate this issue, by revealing multigap features in the excitation spectrum and by providing information about the pairing symmetry. For example, quasiparticle tunneling experiments on MgB 2 have revealed multiple swave gaps arising from multiband coupling [17,18]. In the case of YBCO, c-axis tunneling spectroscopy experiments have revealed multiple spectral features in addition to the predominant d-wave gap [19,20,21,22]. Since multigap spectra could arise from multiband coupling, it would be helpful to understand the origin of these additional spectral features. Furthermore, since both multiband coupling in general [23] and pairing symmetry in the cuprates may vary with carrier doping [24], a detailed study of the spectral evolution with doping could yield important insights on the pairing in YBCO.In this Letter, we present a scanning tunneling spectroscopy (STS) study of Ca-doped c-axis YBCO films at 4.2K. The measured spectra show main-gap, sub-gap and satellite features which scale similarly in energy as a function of Ca-doping, suggesting that they are associated with a single pairing energy. The data i...