The electron mobility in HfO 2 /In 0.53 Ga 0.47 As n-type metal-insulator-semiconductor field-effect transistors (nMISFETs) has been found to be significantly enhanced in the sub-1.0 nm equivalent oxide thickness (EOT) regime by annealing before the atomic layer deposition (ALD) of the HfO 2 gate dielectric. XPS measurements revealed that the predeposition annealing increased the amount of GaO x and reduced the amount of AsO x at the MIS interface, which is considered to reduce the trapped charge density and enhance the mobility, especially in the low-surface-carrierdensity region.