Thirty-one millet cultivars grown in Northern Nigeria were evaluated for physical properties and chemical composition. The physico-chemical characteristics were also correlated. There were wide variations in thousand-kernel weight (8.1712.1 g) and volume (5.8710.0 ml), grain hardness (30.3768.0 N), per cent floaters (31.0795.0%), in addition to considerable variations in protein (9.6712.7%), fat (3.375.2%), crude fibre (1.274.4%) and tannin (0.072.8% catechin equivalent) contents. The grain hardness correlated positively with crude protein (r ¼ 0.687, P < 0.01). Crude protein content correlated positively with grain major diameter (r ¼ 0.538, P < 0.01), thickness (r ¼ 0.529, P < 0.01) and correlated negatively with carbohydrate (r ¼ À 0.473, P < 0.01). The density of the grain showed significant positive correlation, with grain hardness (r ¼ 0.435, P < 0.01), grain thickness (r ¼ 0.568, P < 0.01) and moisture content (r ¼ 0.430, P < 0.01) but negative correlated (r ¼ À 0.403, P < 0.01) with per cent floaters.