Optical voltage sensors are widely applied in the grid due to their excellent resistance to interference, low cost, small volume, and simple structural design. We explore the effect of FBG spectral parameters on sensor performance through simulation and measurement on the PZT-FBG voltage sensing experimental platform. The experimental results indicate that, for the sensor to function properly, the selection of the reference FBGs' center wavelength should not be located in the sensor's invalid region, and is recommended to be not within the range of -0.009nm to +0.066nm around the sensing FBG.