The absolute field-ionization yields of gas-and foil-excited Rydberg states are measured for different fast beam ions. From the yields a direct comparison of the quantum-state populations of high-rt states in > 100) produced by gas and foil excitation could be obtained. Model calculations are consistent with the high-n states being predominantly produced by excitation of the projectile or capture of target electrons in the last layers of the solid target.PACS numbers: 34.50.Fa, 34.60.+Z, 34.70.+e Near-threshold excitation, where electron capture into projectile-centered continuum or Rydberg states occurs in interactions of fast highly charged projectiles with solids, has been intensively investigated for some time. l Yet there is still no sufficient theoretical model to account for the various experimental findings. Studies concerned with the formation of Rydberg states (highly excited hydrogenlike states with large n quantum numbers) in fast ions emerging from foil targets help to provide an understanding of the processes involved in the threshold excitation in ion-solid interactions. 2 Since Rydberg states have considerably larger electronic orbitals than the lattice spacings in a solid, it is assumed that the Rydberg states are formed by collisional interactions in the last layers of the penetrated solid. One of the major questions addressed in this research is the effect of various bulk and surface processes in the ion-solid interaction on the population of Rydberg states, the angular distribution of convoy electrons, and their mean free path. Burgdorfer and co-workers 3 have developed a classical transport theory for electrons near threshold under the influence of stochastic scattering processes in the solid and a strong ionic Coulomb field. This approach may illuminate the problem of the stability of Rydberg orbits under the influence of stochastic perturbations as well as the transmission of convoy electrons through solids.Recently reported results, where the delayed Lyman-a and -p radiation has been measured from fast d> -10 a.u.) foil-excited ions, suggested that the Rydberg-state production accentuates high-/ states and is more than 2 orders of magnitude larger than could be explained by last-layer electron capture. 4 Measurements of the light emission from foil-excited Rydberg states near the yrast line in fast F-and Si-beam ions have also been reported recently. 2 In both cases, the data were described quite well with an empirical parametrization for the average population per nl Rydberg state, with the light emission showing a dependence on the core charge of the penetrating ions as well as on the nuclear charge. This is consistent with a picture where electron capture dominates the production of Rydberg states. The Rydbergstate population of a certain final charge state seems to be almost strictly proportional to the corresponding population of a given core-charge-state fraction. It is, however, not possible to distinguish between capture of target electrons and recapture of cusp electrons or suc...