Effects of resonant magnetic perturbation (RMP) field on impurity radiation, divertor footprint distribution, and core plasma transport are investigated in the detachment discharges of LHD. The RMP with m/n = 1/1 mode creates edge magnetic island in the stochastic layer, which enhances the impurity emission from low charge states, C 2+ and C 3+ , and then triggers detachment transition. The emission from the higher charge states, C 4+ and C 5+ , implies enhanced penetration of impurity during detachment phase with RMP. The toroidal divertor particle flux distribution exhibits n = 1 mode structure in both attached and detached phases, but with a large toroidal phase shift between the two phases. The distribution in the attached phase is well correlated with magnetic footprint of field line connection length calculated by the vacuum approximation. During the detached phase, however, the phase shift is not well explained by the vacuum approximation, where significant plasma response to the external RMP is observed. The energy confinement time becomes systematically shorter with RMP application due to the shrinkage of plasma volume caused by the edge magnetic island. On the other hand, the pressure profile during detachment with RMP is found to be more peaked than without RMP. The analysis with the core transport code TASK3D, taking into account heating profiles of NBI, shows no significant transport degradation during detachment with RMP application, whilst the enhanced radiation, the reduced divertor flux, and the possible impurity penetration.