2019
DOI: 10.2472/jsms.68.13
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Effects of Crosslink Density on Plastic Flow of Glassy Epoxy Networks

Abstract: Steady plastic flow of glassy epoxy networks having various crosslink density was analyzed with Eyring equation to discuss the effect of crosslinked molecular structures on nonlinear viscoelastic behavior of glassy polymers in terms of strain-induced structural change. Steady flow stresses of the glasses were calculated with modified stress optical rule (MSOR) from stress and birefringence data observed during uniaxial stretching. Activation enthalpy DH, activation entropy DS and activation volume va of the st… Show more

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