The effects of adding
acetylene to the fuel stream on soot formation
and flame properties were investigated numerically in a laminar axisymmetric
coflow ethylene/air diffusion flame using the open-source flame code
Co-Flame in conjunction with an elementary gas-phase chemistry scheme
and detailed transport and thermodynamic database. Radiation heat
transfer of the radiating gases (H
2
O, C
2
H
2
, CO, and CO
2
) and soot was calculated using a
statistical narrow-band correlated-
k
-based wide band
model coupled with the discrete-ordinates method. The soot formation
was described by the consecutive steps of soot nucleation, surface
growth of soot particles via polycyclic aromatic hydrocarbons (PAHs)-soot
condensation or the hydrogen abstraction acetylene addition (HACA)
mechanism, and soot oxidation. The added acetylene affected the flame
structure and soot concentration through not only chemical reactions
among different species but also radiation effects. The chemical effect
due to the added acetylene had a significant impact on soot formation.
Specifically, it was confirmed that the addition of 10% acetylene
caused an increase in the peak soot volumetric fraction (SVF) by 14.9%
and the peak particle number density by about 21.1% (
z
= 1.5 cm). Furthermore, increasing acetylene concentration led to
higher concentrations of propargyl, benzene, and PAHs and consequently
directly enhanced soot nucleation rates. In addition, the increased
H mole fractions also accentuated the soot surface growth. In contrast,
the radiation effect of the addition of 10% acetylene was much weaker,
resulting in slightly lower flame temperature and SVF, which in turn
reduced the radiant heat loss.