Although dielectronic and radiative recombination are usually treated as distinct noninterfering processes, Alber, Cooper, and Rau [Phys. Rev. A 30, 2845 (1984)] have recently presented a scattering-or S-matrix analysis which provides a unified description of these processes. This description employs a diagonalization of the atom plus radiation field Hamiltonian using a limited basis set consisting of one discrete autoionizing state, a single-electron continuum, and a single-photon continuum. In the present work we extend M&lier scattering operator and resolvent operator techniques, which have previously been used to discuss the decay of prepared systems, in order to provide an Smatrix analysis of the electron-ion photorecombination process near an isolated autoionizing resonance. We explicitly allow for degenerate magnetic sublevels of the atomic system and for multiple angular momentum contributions in the partial-wave expansion of the electron-continuum eigenstate. After the introduction of the pole approximation, in which only the 6-function term is retained in the evaluation of the various self-energies that occur in the diagonalization of the Hamiltonian for the combined many-electron radiation-field system, we obtain the total electron-ion photorecornbination cross section as the sum of the radiative and dielectronic recombination contributions together with the conventionally ignored interference term. The radiative and dielectronic recombination cross sections reduce to the familiar forms when the continuum-continuum coupling eftects are neglected. Alternatively, the combined cross section for the entire electron-ion photorecombination process may be represented by a modified Fano line profile, which is shifted and broadened as a result of the coupling between the autoionization and radiation continua. Recombination processes that involve more than a single state of the initial ion, of the autoionizing resonance, or of the final system can be treated by appropriately augmenting the unperturbed basis set. It is anticipated that the eft'ects of the interference between radiative and dielectronic recombination and of the continuum-continuum coupling will be most important for individual transitions involving low-lying autoionizing levels and will probably be negligible for the total dielectronic recombination rates due to the highly excited levels.