Abstract:The effects of adding Na2 WO4. 2H2O and SiC powder to the electrolyte on the characteristics of ceramic coatings on Al based alloys formed by microarc oxidation were studied. The ceramic coating quality was improved by the two additives, but the addition of Na2 WO4. 2H2O was more effective, as it improved the formation of Al2O3 phase in the ceramic coating, increased the ratio of the internal dense region to the whole ceramic coating, optimised the ceramic coating phase structure, and improved its wear resista… Show more
“…(Wei et al, 2004;Curran and Clyne, 2005a,b;Wang et al, 1999). It was reported Ma et al, 2006) that higher current density and lower solution temperature benefit film growth.…”
“…(Wei et al, 2004;Curran and Clyne, 2005a,b;Wang et al, 1999). It was reported Ma et al, 2006) that higher current density and lower solution temperature benefit film growth.…”
“…[9,10,11] The research related to development of the MAO process has intensified in the last 5 years. Voevodin and co-workers in the United States, [12] Matthews and co-workers in the United Kingdom, [13] Wang and co-workers in China, [14] Sundararajan et al in India, [15,16] and Mecuson et al in France [17] have contributed to the further development of the MAO technique in conjunction with improving our understanding of the mechanism of coating formation and coating properties. The overall wear resistance offered by the MAO coatings under the abrasion, erosion, and sliding wear modes was found to be comparable to that of the bulk alumina and better than the thermal-sprayed alumina and hard anodized coatings.…”
The micro arc oxidation (MAO) technique is being increasingly recognized as a novel and ecofriendly means of depositing dense ceramic oxide coatings on Al and its alloys. In the present study, the deposition kinetics, surface roughness, morphology, phase distribution and the microhardness of the MAO coatings deposited on ten different commercially available Al substrates having widely differing chemical composition has been investigated. Further, the tribological properties of the coatings obtained on different Al alloys in comparison with the bare substrates have also been evaluated using dry sand abrasion, solid-particle erosion and pinon-disc dry sliding wear tests. The results clearly demonstrate that the alloying elements added to the Al substrate substantially influence the MAO coating deposition kinetics and coating properties. In the case of Al-Si alloys, the coating deposition kinetics is non-linear and the Al 6 Si 2 O 13 (mullite) is observed to form. With increasing Si content, the corresponding mullite phase also increases. Increasing mullite content in the coating adversely affects the tribological performance. Excepting Al-Si alloys, all other alloys investigated including commercial purity Al exhibit linear coating deposition kinetics. Of all the alloys investigated, Al-Li alloy exhibits the highest coating deposition rate and the 6061 T6 Al alloy exhibits the best coating properties.
“…Wang et al [20] and Zheng et al [21] have found that Na 2 WO 4 could improve the formation of Al 2 O 3 phase in the ceramic coating and improve its wear resistance. Butyagin et al [22] reveal that introducing compounds of transition metals into the solution can lead to the changes in the coatings' structure, and the coatings obtained are capable of enduring higher thermocyclic loads.…”
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