Effective Dipole Moment and Band Intensities Problem for Carbon Dioxide

Effective Dipole Moment and Band Intensities of Nitrous Oxide

“…So the polyads can be labeled by this number P. In order to make easier comparisons with other papers, we have given up the notation previously used in the case of the carbon dioxide molecule (17) for labeling the levels within a given polyad. Instead we have used the customary notation £ 1 £ 2 ᐉ 2 £ 3 in which the pseudo quantum numbers £ 1 , £ 2 , £ 3 fulfill Eq.…”

“…Using the effective Hamiltonian and the effective dipole moment approach described in our recent papers (15)(16)(17) the square of rotationless electric-dipole transition moment ÉR Dᐉ 2 N=1=RN1 É 2 for the vibrational transition N1 R N1 can be expressed as…”

Dipole-Moment Derivatives of Nitrous Oxide

“…The reduction has been achieved by setting the x ll e and F e (3) parameters to zero, so one finds from Eqs. [18] and [19] the parameters of the generators:…”

“…The quantum number functions f ⌬V ⌬l 2 (V, l 2 ) are listed in Table I of Ref. (19) for small values of ⌬V and the parameters M ⌬V ⌬l 2 , i ⌬V , a K ⌬V can be expressed in terms of force field constants and constants determining the dipole-moment function.…”

Absorption spectra of 12C16O2 and 13C16O2 near 1.05μm

“…Using the effective operators approach presented, for example, in [8][9][10], we have performed the line intensity fittings for both isotopic species. The observed bands belong to DP = 13 series of transitions according to our classification given in [9,10].…”