“…So the polyads can be labeled by this number P. In order to make easier comparisons with other papers, we have given up the notation previously used in the case of the carbon dioxide molecule (17) for labeling the levels within a given polyad. Instead we have used the customary notation £ 1 £ 2 ᐉ 2 £ 3 in which the pseudo quantum numbers £ 1 , £ 2 , £ 3 fulfill Eq.…”
Section: Least-squares Fittingsmentioning
confidence: 99%
“…Using the effective Hamiltonian and the effective dipole moment approach described in our recent papers (15)(16)(17) the square of rotationless electric-dipole transition moment ÉR Dᐉ 2 N=1=RN1 É 2 for the vibrational transition N1 R N1 can be expressed as…”
“…So the polyads can be labeled by this number P. In order to make easier comparisons with other papers, we have given up the notation previously used in the case of the carbon dioxide molecule (17) for labeling the levels within a given polyad. Instead we have used the customary notation £ 1 £ 2 ᐉ 2 £ 3 in which the pseudo quantum numbers £ 1 , £ 2 , £ 3 fulfill Eq.…”
Section: Least-squares Fittingsmentioning
confidence: 99%
“…Using the effective Hamiltonian and the effective dipole moment approach described in our recent papers (15)(16)(17) the square of rotationless electric-dipole transition moment ÉR Dᐉ 2 N=1=RN1 É 2 for the vibrational transition N1 R N1 can be expressed as…”
“…The reduction has been achieved by setting the x ll e and F e (3) parameters to zero, so one finds from Eqs. [18] and [19] the parameters of the generators:…”
Section: Reduction Of the Effective Operatorsmentioning
confidence: 99%
“…The quantum number functions f ⌬V ⌬l 2 (V, l 2 ) are listed in Table I of Ref. (19) for small values of ⌬V and the parameters M ⌬V ⌬l 2 , i ⌬V , a K ⌬V can be expressed in terms of force field constants and constants determining the dipole-moment function.…”
“…Using the effective operators approach presented, for example, in [8][9][10], we have performed the line intensity fittings for both isotopic species. The observed bands belong to DP = 13 series of transitions according to our classification given in [9,10].…”
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