2017
DOI: 10.1002/slct.201701631
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Effective Catalytic Reduction of Methyl Orange Catalyzed by the Encapsulated Random Alloy Palladium‐Gold Nanoparticles Dendrimer.

Abstract: A series of stable and well‐dispersed random alloy nanoparticles of palladium and gold was synthesized by a template method using dendrimers. The synthesized nanoparticles were qualitatively and quantitatively characterized by UV‐Vis spectrophotometry (UV‐Vis), High‐resolution transmission electron spectroscopy (HR‐TEM), energy dispersed X‐ray spectroscopy (EDS) and inductively coupled plasma optical emission spectrometry (ICP‐OES). Metal nanoparticles size (Pd55Au55/Dens‐OH ((2.21 ± 0.41) nm)) were significan… Show more

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Cited by 29 publications
(20 citation statements)
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References 50 publications
(70 reference statements)
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“…Palladium proved more suitable over silver and platinum and as expected from the stereochemical point of view the longer alkyl chains slowed the diffusion of the bulky pollutant [113]. The formation of bimetallic Pd/Au nanoparticles into PAMAM-OH G6 produced an additional successful suggestion for methyl orange degradation that established the excellent potential of Pd NPs [114].…”
Section: Treatment Of Pigmentsmentioning
confidence: 73%
“…Palladium proved more suitable over silver and platinum and as expected from the stereochemical point of view the longer alkyl chains slowed the diffusion of the bulky pollutant [113]. The formation of bimetallic Pd/Au nanoparticles into PAMAM-OH G6 produced an additional successful suggestion for methyl orange degradation that established the excellent potential of Pd NPs [114].…”
Section: Treatment Of Pigmentsmentioning
confidence: 73%
“…Palladium proved more suitable over silver and platinum and as expected from the stereochemical point of view the longer alkyl chains slowed the diffusion of the bulky pollutant [104]. The formation of bimetallic Pd/Au nanoparticles into PAMAM-OH G6 produced an additional successful suggestion for methyl orange degradation that established the excellent potential of Pd NPs [105].…”
Section: Treatment Of Pigmentsmentioning
confidence: 73%
“…The catalytic degradation of methyl orange results in the formation of sulfanilic acid and aromatic amines, degradation of methylene blue results in leucomethylene blue, ,,, and that of 4-nitrophenol results in 4-aminophenol. The byproducts of the catalytic degradation are colorless and have various industrial and medicinal applications, although toxic in higher amounts. ,, , , This suggests that the processed water can be utilized by industries for the manufacturing of commercially relevant products . The reaction kinetics were monitored using UV–vis spectroscopy.…”
Section: Resultsmentioning
confidence: 99%