Effective Adsorption of Diesel Oil by Crab-Shell-Derived Biochar Nanomaterials

Cai, Lu; Zhang, Yan; Zhou, Yarui; Zhang, Xiaodie; Ji, Lili; Song, Wen‐Dong; Zhang, Hailong; Liu, Jianshe

doi:10.3390/ma12020236

Cited by 70 publications

(39 citation statements)

References 55 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Figure 1 shows the FTIR results for the identification of the present functional groups in the PMT and CCLHR species. In the range of 3000–3720 cm −1 , a broad and low intensity band was observed, peaks at 3330 cm −1 (Figure 1a) and 3320 cm −1 (Figure 1b), characterizing the presence of O–H (alcohols and phenols) [44]. Peaks were also observed at 1630 cm −1 (Figure 1a) and 1613 cm −1 (Figure 1b), which indicated the C = O stretching in organic groups of carboxyl and bending vibration of the functional group –OH [45].…”

Section: Resultsmentioning

confidence: 99%

See 1 more Smart Citation

Biosorption of Methylene Blue Dye Using Natural Biosorbents Made from Weeds

et al. 2019

View full text Add to dashboard Cite

The purpose of this work is to make use of vegetables that, although widely found in nature, there are few applications. The weeds used here, Cyanthilium cinereum (L.) H. Rob (CCLHR) and Paspalum maritimum (PMT) found in the Amazon region of Belém state of Pará-Brazil, contribute to the problem of water contamination by the removal of the methylene blue dye through the biosorption process, taking advantage of other materials for economic viability and processing. The influences of parameters such as, biosorbent dose, contact time, and initial concentration of dye were examined. The characterizations were realized using SEM to verify the morphology of the material and spectroscopy in the FTIR region. As for the adsorption mechanism, the physical adsorption mechanism prevailed. The time required for the system to reach equilibrium for both biosorbents was from 50 min, following a kinetics described by the pseudo-second order model. The adsorption isotherm data for PMT were better adjusted to the Langmuir model and the biosorption capacity ( q m a x ) value was (56.1798 mg/g). CCLHR was better adjusted to the Freundlich model and its maximum biosorption capacity was 76.3359 mg/g. Thus, these weed species are promising for the biosorption of methylene blue dye in effluents.

show abstract

Section: Resultsmentioning

confidence: 99%

“…According to Cai L. et al [44], the linearized form of Equation (6) is described by:logqe=logkF+1nlogce…”

Section: Resultsmentioning

confidence: 99%

Biosorption of Methylene Blue Dye Using Natural Biosorbents Made from Weeds

et al. 2019

View full text Add to dashboard Cite

show abstract

“…Ngarmkam and coworkers [46] carried out research on the removal and recovery of residual oil onto palm shell-based carbon; the equilibrium adsorption capacity of samples reached 30–90 mg/g. Cai et al [47] explored the adsorption properties of diesel oil on modified crab shell-activated biochar carbon; the adsorption capacity was 93.9 mg/g. Although the oil sorption capacity of MAFC obtained in this experiment was 45.5 mg/g, which is relatively low compared with other adsorbents, waste fish bone materials have potential to be applied for the removal of oil, at no cost.…”

Section: Resultsmentioning

confidence: 99%

Facile Preparation of Charcoal Nanomaterial from Fishery Waste with Remarkable Adsorption Ability

et al. 2019

Self Cite

View full text Add to dashboard Cite

In this study, modified activated fishbone charcoal (MAFC) was successfully prepared to remove emulsified oil from oily wastewater. Various characteristic techniques, including SEM, XRD, FTIR, and BET, were employed to investigate the morphology, texture, and surface properties of as-prepared samples. BET results demonstrated that the specific surface area of fishbone charcoal increased from 69.8 m2/g to 206.0 m2/g after treatment with K2CO3 as an activating agent, while the total pore volume of MAFC increased from 0.003 cm3/g to 0.3 cm3/g, accompanied by the formation of abundant pore structures. It was observed that 90.1% of emulsified oil (100 mg/L) was successfully removed by MAFC under our experimental conditions. The results of a kinetic and isotherm model analysis indicated that the adsorption experimental data were not only consistent with the Langmuir adsorption isotherm but were also well-described by the pseudo-second-order adsorption model. It is expected that this highly efficient and inexpensive MAFC can be a promising bio-adsorbent for removing organic pollutants from industrial wastewater.

show abstract

“…the semi crystalline structure of chitin). Finally, the diffraction peak of the (104) plane is the most intense peak for calcite in CCM, indicating that CaCO 3 in the crab carapace is in crystallised calcite form along the biopolymer chains (Cai et al 2019).…”

Section: Materials Characterisationmentioning

confidence: 95%

“…The normalised XRPD patterns show the presence of both an amorphous phase, which is associated with the organic component of the material, e.g. chitin/chitosan polymer and a crystalline phase, which was identified as calcite (Swanson et al 1953;Zhou et al 2016;Cai et al 2019). The broad diffraction peaks observed at around 9.6°and 19°in the raw material (representing the amorphous chitin structure) are found to sharpen after activation, suggesting the material has crystallised during the activation process (Arulvel et al 2017).…”

Section: Xrpdmentioning

confidence: 99%

Synthesis optimisation and characterisation of chitosan-calcite adsorbent from fishery-food waste for phosphorus removal

Pap

Kirk

Sekulić

et al. 2020

Environ Sci Pollut Res

View full text Add to dashboard Cite

Here, Box-Behnken design (BBD) approaches were utilised to optimise synthesis methodology for the chitosan-calcite rich adsorbent (CCM) made from fishery-food waste material (crab carapace), using low-temperature activation and potassium hydroxide (KOH). The effect of activation temperature, activation time and impregnation ratio was studied. The final adsorbent material was evaluated for its phosphorus (P) removal efficiency from liquid phase. Results showed that impregnation ratio was the most significant individual factor as this acted to increase surface deacetylation of the chitin (to chitosan) and increased the number of amine groups (-NH 2 ) in the chitosan chain. P removal efficiency approached 75.89% (at initial P concentration of 20 mg/L) under optimised experimental conditions, i.e. where the impregnation ratio for KOH:carapace (g/g) was 1:1, the activation temperature was 105°C and the activation time was 150 min. Predicted responses were in good agreement with the experimental data. Additionally, the pristine and CCM material were further analysed using scanning electron microscopy with energy dispersive X-ray spectroscopy (SEM/EDX), Brunauer-Emmett-Teller technique (BET), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and thermal gravimetric analysis (TGA). Characterisation showed enhancements in surface chemistry (introducing positively charged amine groups), textural properties and thermal stability of the CCM.

show abstract

Effective Adsorption of Diesel Oil by Crab-Shell-Derived Biochar Nanomaterials

Cited by 70 publications

References 55 publications

Biosorption of Methylene Blue Dye Using Natural Biosorbents Made from Weeds

Biosorption of Methylene Blue Dye Using Natural Biosorbents Made from Weeds

Facile Preparation of Charcoal Nanomaterial from Fishery Waste with Remarkable Adsorption Ability

Synthesis optimisation and characterisation of chitosan-calcite adsorbent from fishery-food waste for phosphorus removal

Contact Info

Product

Resources

About