Effect of Zinc Oxide on the Thermal Decomposition of Dimethyl Sulfoxide

Wu, Wei; Guo, Zichao; Chen, Liping; Chen, Wang-hua; Weng, Shichun; Li, Huabo

doi:10.1021/acs.oprd.1c00275

Cited by 2 publications

(1 citation statement)

References 22 publications

(38 reference statements)

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“…For example, Yang and Sheng , have comprehensively reviewed the potential safety hazards of dimethyl sulfoxide (DMSO) and N , N -dimethylformamide (DMF) in various chemical reactions. They proposed that DMSO and DMF are incompatible with a wide variety of substances, which has resulted in many incidents. − …”

Section: Introductionmentioning

confidence: 99%

Compatibility Study between 50% H₂O₂/H₂SO₄ Solution and Some Common Organic Solvents

Weng,

Zhou,

Tian

et al. 2024

Org. Process Res. Dev.

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In this article, a mixture of sulfuric acid and 50% hydrogen peroxide solution was used to produce Caro's acid, which serves as an oxidant frequently encountered in the fine chemical industry. The chemical compatibility between 50% H 2 O 2 /H 2 SO 4 and organic solvents is an important safety issue. The compatibility of 50% H 2 O 2 /H 2 SO 4 and several organic solvents, including ethanol, acetonitrile, ethyl acetate, DMF, dichloroethane, DMSO, ether, and toluene, was studied by reaction calorimetry and thermal analysis techniques. It was found that the first five solvents presented good compatibility with 50% H 2 O 2 /H 2 SO 4 . DSC tests indicated that these five solvents almost did not react with 50% H 2 O 2 /H 2 SO 4 before the onset decomposition temperature of 50% H 2 O 2 /H 2 SO 4 (∼93.3 °C). RADEX tests showed that the reactions of 50% H 2 O 2 /H 2 SO 4 with these solvents released heats from 800 to 1100 J g −1 , and the pressure effect was obvious for these mixtures. In contrast, the last three solvents, namely, DMSO, ether, and toluene, were incompatible with 50% H 2 O 2 /H 2 SO 4 , exhibiting a significant exothermic signal at lower temperatures. Most interestingly, the mixture of DMSO and 50% H 2 O 2 /H 2 SO 4 presented a thermal runaway phenomenon below 40 °C. The causes of this thermal runaway incident were confirmed to be the oxidation of DMSO by Caro's acid. Reaction calorimetry tests also indicated that the oxidation rate of DMSO was fast even at 40 °C, and the adiabatic temperature rise for the oxidation of DMSO was higher than 400 K. KEYWORDS: compatibility, 50 percent H 2 O 2 /H 2 SO 4 , organic solvents, thermal runway reaction, thermal risk

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Section: Introductionmentioning

confidence: 99%

Compatibility Study between 50% H₂O₂/H₂SO₄ Solution and Some Common Organic Solvents

Weng,

Zhou,

Tian

et al. 2024

Org. Process Res. Dev.

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In Situ Formed Robust Solid Electrolyte Interphase with Organic–Inorganic Hybrid Layer for Stable Zn Metal Anode

Lin,

Li,

Wang

et al. 2024

Small Methods

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Stabilizing the Zn anode/electrolyte interface is critical for advancing aqueous zinc ion storage technologies. Addressing this challenge helps minimize parasitic reactions and controls the formation of Zn dendrites, which is fundamental to achieving highly reversible Zn electrochemistry. In this study, 2% by volume of dimethyl sulfoxide (DMSO) is introduced into the baseline zinc sulfate (ZS) electrolyte, which acts as an efficient regulator to form a robust solid–electrolyte interphase (SEI) on the Zn anode. This innovative approach enables uniform Zn deposition and does not substantially modify the Zn2+ solvation structure. The Zn||Zn symmetric cell exhibits an extended cycle life of nearly one calendar year (>8500 h) at a current density of 0.5 mA cm−2 and an areal capacity of 0.5 mAh cm−2. Impressive full cell performance can be achieved. Specifically, the Zn||VS2 full cell achieves an areal capacity of 1.7 mAh cm−2, with a superior negative‐to‐positive capacity ratio of 2.5, and an electrolyte‐to‐capacity ratio of 101.4 µL mAh−1, displaying remarkable stability over 1000 cycles under a high mass loading of 11.0 mg cm−2 without significant degradation. This innovative approach in electrolyte engineering provides a new perspective on in situ SEI design and furthers the understanding of Zn anode stabilization.

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Effect of Zinc Oxide on the Thermal Decomposition of Dimethyl Sulfoxide

Cited by 2 publications

References 22 publications

Compatibility Study between 50% H₂O₂/H₂SO₄ Solution and Some Common Organic Solvents

Compatibility Study between 50% H₂O₂/H₂SO₄ Solution and Some Common Organic Solvents

In Situ Formed Robust Solid Electrolyte Interphase with Organic–Inorganic Hybrid Layer for Stable Zn Metal Anode

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Effect of Zinc Oxide on the Thermal Decomposition of Dimethyl Sulfoxide

Cited by 2 publications

References 22 publications

Compatibility Study between 50% H2O2/H2SO4 Solution and Some Common Organic Solvents

Compatibility Study between 50% H2O2/H2SO4 Solution and Some Common Organic Solvents

In Situ Formed Robust Solid Electrolyte Interphase with Organic–Inorganic Hybrid Layer for Stable Zn Metal Anode

Contact Info

Product

Resources

About

Compatibility Study between 50% H₂O₂/H₂SO₄ Solution and Some Common Organic Solvents

Compatibility Study between 50% H₂O₂/H₂SO₄ Solution and Some Common Organic Solvents