“…Over the last few decades, numerous techniques have been used to prepare high purity magnesium aluminate spinel powder including solid-state synthesis hydrothermal synthesis [14], co-precipitation [15][16][17], microemulsion technique [18], microwave-assisted combustion processing [19], plasma spray decomposition [20,21], sol-gel of double or semi-alkoxides [22][23][24], the citrate-nitrate route [25,26], organic gel-assisted citrate process [27], aerosol method [28], freeze drying [29], decomposition of organometallic compounds [30][31][32][33], mechaniochemical synthesis [34,35], mechanical activation [1] and others [36][37][38]. Among them solid-state synthesis is the most common rout to produce commercial MA spinel.…”