Abstract:Single crystal EPR and optical studies of a mixed ligand zinc(II) complex doped with VO(II) ion is carried out to establish the structural properties. The angular variation of vanadyl hyperfine lines indicates a single site, with spin Hamiltonian parameters as: g xx = 1.985, g yy = 1.979, g zz = 1.943; A xx = 8.71, A yy = 6.41 and A zz = 17.80 mT. By comparing the direction cosines of principal g and A values with the direction cosines of metalligand bonds, it has been confirmed that the vanadyl ion has entere… Show more
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