Abstract. Presents the results of mathematical simulation of the condensation process of sulphur dioxide and water vapor on the condensation nuclei surface under the action of natural factors. Numerical investigations were carried out for the summer at a moderate speed of the wind. The influence of the parameter of condensation on the speed of the process of sulfuric acid drops formation in the air space was analyzed. Time ranges, sufficient for the formation of the acid rain sedimentation in the atmosphere, adjacent to the areas of thermal power station work were established. It is shown that the speed of air masses movement effects on the process of acid anthropogenic admixtures dispersion in the atmosphere. Approbation of the obtained results was carried out by checking the difference scheme conservative and solution of test problems.A significant contribution to the formation of sulfuric acid in the boundary layer of the atmosphere is contributed by thermal power plants [1]. When burning the natural fuel of power plants in the environment there are different pollutants [2]. Under the influence of natural factors the combustion products of coals may condense on the water droplets presenting in the atmosphere and reach the Earth's surface [3]. Most of them refers to the number of toxic, and even at relatively low concentrations cause the adverse effects on nature and human life [1,2]. Table 1 shows the values of acceptable amounts of some contaminants contained in the flue gas in power station.In this paper we study the processes of condensation of sulphur trioxide SO 3 and water vapor H 2 O. Sulphur dioxide is formed in flues boilers of power plants by partial oxidation of SO 2 (up to 5% of the total SO 2 ) from the combustion of high-sulphur fuels, and belongs to a class of mild-hazard products [1,2].Earlier in [5][6][7] the process of acid rain formation in the airspace adjacent to the power plants, at different air temperatures and wind speeds was investigated. It was intended that the formation of sulfuric acid drops occurs only due to condensation of sulfuric anhydride on the condensation nuclei surface.In real practice the atmosphere always contains water vapors of natural origin [7]. In addition, a significant increase of the water vapor concentration in the air is possible in areas adjacent to the power plants by emissions of H 2 O due to the work of the heat engineering equipment of the station [1]. The analysis of processes of sulfuric acid drops formation in the air upon jointly proceeding processes of condensation of SO 3 and H 2 O vapors on the condensation nuclei surface is of interest. This is an Open Access article distributed under the terms of the Creative Commons Attribution License 4.0, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.