“…These are (i) sonochemical preparation, (ii) co-precipitation, (iii) electro-less co-deposition, (iv) hydro-thermal synthesis, (v) spray pyrolysis , (vi) tape casting, (vi) mechanical mixing or ball milling of individual powders followed by compaction and sintering, and (vii) combustion synthesis etc [3,13]. Since properties of Ni/YSZ anodes are mostly dependent on the particle size and the microstructure of the cermets, among various methods stated above, combustion synthesis is a simple and cost effective to produce very fine, homogeneous with high purity, a narrow particle size distribution with high specific surface area and highly crystalline powders [3,13,14] without any intermediate step. It consists of a self-propagating high temperature synthesis (SHS), discovered by Merzhanov and co-workers, which involves a wide variety of chemical routes and products [14].…”