Compressional-and shear-wave velocities were measured in the laboratory in seven sandstones (porosities ranging from 6 to 29%) and one unconsolidated sand (37% porosity) saturated with n-hexadecane (C 16H34) both before and after CO 2 flooding. CO 2 flooding decreased compressional-wave velocities significantly, while shear-wave velocities were less affected. The magnitude of these effects was found to depend on confining and pore pressures, temperature, and porosities of the rocks. The experimental results and theoretical analysis show that the decreases in compressional-wave velocities caused by CO 2 flooding may be seismically resolvable in situ. Therefore, seismic-especially high-frequency, high-resolution seismic-methods may be useful in mapping and locating CO 2 zones, tracking movements of CO 2 fronts, and monitoring flooding processes in reservoirs undergoing CO 2 flooding.
IntroductionOn average, nearly three-quarters of the hydrocarbons in place are not recoverable by conventional methods. Developments in new EOR methods are therefore becoming more and more important to scientists and engineers. One EOR method uses high-pressure CO 2 injection to recover oils left behind by conventional recovery from reservoir rocks. Of course, not all reservoirs are suitable for CO 2 floodings or for other EOR methods, but considerable effort is currently being made in the oil industry to implement large-scale CO 2 injection projects, in addition to relatively smaller ongoing CO 2 injection pilots. I With development of better EOR methods, methods of monitoring EOR processes are also becoming important because monitoring will open the door for control and modification of recovery processes. In our view, seismic methods are among the more promising monitoring methods. Seismic field survey is relatively economical, and the acquisition and processing of field data are fairly routine. Furthermore, seismic monitoring does not generally require shutting in wells, does not disturb reservoir fluid flows (because seismic waves usually cause very small strains in reservoir rocks), and does not cause precipitation of chemicals in the reservoir.The effectiveness of seismic methods in monitoring EOR processes depends on the velocity and amplitude changes of the seismic waves caused by these processes. Intuitively, the injected CO 2 will increase the compressibility and change the density (either increase or decrease, depending on the pore pressure) of reservoir rocks. These changes will in turn affect the propagation characteristics of the seismic waves. The quantitative effects of CO 2 flooding on wave characters are not well known, however, and no laboratory or field experiments on such effects have thus far been published. Before applying seismic methods in the field, it is therefore necessary to investigate the effects of CO 2 flooding on the seismic properties of reservoir rocks saturated with hydrocarbons in the laboratory .Both compressional-and shear-wave velocities in seven sandstones of various porosities and compressiona...