Effect of temperature on anti-corrosion properties of aluminum alloy anodized by sulphuric acid

Abstract

Temperature is one of the most important parameters in anodizing treatments of aluminum alloys as it directly affects the quality of the anodic coatings. This research study has examined and investigated the effect of this important parameter on the anti-corrosion properties of the anodizing layers of aluminum alloy 5083.The morphology and crystalline structure of anodic oxide layers were characterized respectively by X-ray diffraction, scanning lectron microscopy and EDX analysis. The corrosion behaviour of the alloy, before and after anodization at different temperatures, was analyzed in chlorinated medium using different electrochemical techniques, namely open circuit potential measurement, potentiodynamic polarization and electrochemical impedance spectroscopy. The results showed that temperature has a significant influence on the quality of the anodic oxide layers. Therefore, for a relatively low treatment temperature, the developed anodic films show high surface roughness values and contain fewer pores and defects compared to the films obtained at 20°C. Electrochemical analysis indicates that these films also show good corrosion resistance in the chloride environment. This is reflected by relatively low corrosion current density values as well as relatively high polarization resistance values.