Effect of Temperature and Accelerator on Gel Time and Compressive Strength of Resin Anchoring Agent

Abstract

In this study, we examined the effects of different temperatures and accelerators on the gelation (gel) time and compressive strength of a Polyethylene Terephthalate (PET)-type unsaturated polyester resin anchorage agent. First, the formation temperature of 20–70°C was simulated using self-made test equipment. N,N-Dimethylaniline (DMA), N,N-dimethylp-toluidine (DMT), and hydroquinone were selected as accelerators to determine gel time and heat release peak. The gel time of an anchorage agent is strongly influenced by accelerant and temperature. When DMT, DMA, and hydroquinone were added at the same temperature, the gelation time increased; with increasing ambient temperature, the gelation time of the anchorage agent decreased. The peak exothermic value of the curing reaction was less affected by the accelerator, and the peak exothermic value of the anchoring agent increased with the increase in ambient temperature. Then, the compressive strength of the anchorage agent, maintained at 20, 50, and 80°C for 1.5, 6, 12, and 24 h, was measured. We found that the compressive strength of resin anchorage agent decreased significantly with the increase in temperature, and the addition of DMT can improve the compressive strength of resin anchorage agent slightly at the same temperature conditions. Finally, through Fourier transform infrared scanning analysis, we determined the intrinsic causes of the influence of temperature and accelerator on the gelation time and compressive strength of the anchorage agent. Through SPSS fitting analysis, an empirical formula for predicting gelation time based on ambient temperature is proposed. Our findings provide a basis for reasonable mixing time and support design optimization of anchorage support in deep stratum in high-temperature geothermal environments.

Low-temperature resin embedding of the whole brain for various precise structures dissection

“…DMT was more active and hence more suitable for low-temperature environment than DMA. 26 Here, we added DMT as a new polymerization accelerator for embedding at −20°C. After extensive testing, we found that 0.6% BPO and 0.7% DMT were the optimal concentration combination.…”

Experimental Study of the Failure Mechanism of the Anchorage Interface under Different Surrounding Rock Strengths and Ambient Temperatures

“…e curing dosage of the anchoring agent is 4% of the mass of the resin mortar, the curing time is 180 s, the strength of the anchoring agent is 65 MPa, the elastic modulus is 10.5 GPa, and Poisson's ratio is 0.26. In addition, the compressive strength of the anchoring agent at different temperatures is shown in Table 2 [20,21].…”