Effect of Tannins Addition on Thermal Stability of Furfurylated Wood

Abstract

This article presents the effect of the addition of condensed tannins, used as a reticulation agent, on the polymerization of furfuryl alcohol during wood furfurylation, as well as the effect of these condensed tannins on the thermal stability of modified wood. Three kinds of dicarboxylic acids (adipic acid, succinic acid, and tartaric acid), as well as glyoxal, used as model of a wood reticulation agent, were used to catalyze the polymerization of furfuryl alcohol or tannin-furfuryl alcohol solutions. Impregnation of furfuryl alcohol or tannin-furfuryl alcohol solution into the wood, followed by curing at 103 °C for a specific duration, was performed for the wood modification. The thermal stability of the obtained tannin-furfuryl alcohol polymers and their corresponding modified woods was investigated. The leaching resistance and dimensional stability of the modified woods were also evaluated. Results indicated that the partial substitution of furfuryl alcohol by the tannins improved the polymerization reactivity in conditions where furfuryl alcohol alone did not lead to the formation of a solid polymeric material. The thermal stability and leaching resistance of the furfurylated wood in the presence of tannins were improved. Dimensional stability was also improved for furfurylated samples, but the effect of tannin addition was not so obvious, depending on the acidic catalyst used.

Preparation and Characterization of Biomass Tannin-Based Flexible Foam Insoles for Athletes

“…This foam has attractive properties such as a light weight, excellent refractoriness, and thermal insulation [ 19 , 20 , 21 ]. However, the self-condensation reaction of furfuryl alcohol occurs under acidic conditions, which dominates the reaction, and almost no co-condensation reaction with tannins occurs [ 22 ]. In addition, furfuryl alcohol has no significant reactivity under alkaline conditions, whereas the self-condensation and hydroxymethylation reactions occur mainly under acidic conditions [ 23 ].…”