In this paper, we reported the effect of Cu doping on the structural and dielectric properties of Ba 2 Y 1−x Cu x TaO 6−y (0.00 ≤ x ≤ 0.50) ceramics at room temperature. The copper for yttrium substitution reduces the sintering temperature and leads to structural changes in the Ba 2 YTaO 6 rock-salt crystalline structure. Dielectric permittivity and complex impedance spectroscopy measurements suggested enhancement of the dielectric constant and occurrence of interfacial Maxwell-Wagner polarization.