Effect of Support on Steam Reforming of Ethanol for H2 Production with Copper-Based Catalysts

Abstract

Catalytic studies hydrogen production via steam reforming of ethanol (SRE) are essential for process optimization. Likewise, selecting the ideal support for the active phase can be critical to achieve high conversion rates during the catalytic steam reforming process. In this work, copper-based catalysts were synthesized using two different supports, NaY zeolite and Nb2O5/Al2O3 mixed oxides. The materials were prepared using wet impregnation and characterized for their physicochemical properties using different analytical techniques. Differences in the catalyst morphologies were readily attributed to the characteristics of the support. The Cu/NaY catalyst exhibited a higher specific surface area (210.40 m2 g−1) compared to the Cu/Nb2O5/Al2O3 catalyst (26.00 m2 g−1), resulting in a homogeneous metal dispersion over the support surface. The obtained results showed that, at 300 °C, both the Cu/Nb2O5/Al2O3 and Cu/NaY catalysts produced approximately 50% hydrogen and 40% acetaldehyde, but with significant differences in conversion (6% and 56%, respectively). At 450 °C, a greater product distribution and a 10% higher conversion were observed when the catalyst was supported on NaY compared to Nb2O5/Al2O3. Hence, the performance of copper-based catalysts was influenced significantly by the textural properties of the support.