Effect of structural variability and flexibility of aliphatic diamines on self-assembly of host-guest coordination polymers constructed of copper cyanide networks: Structure study and catalytic activity
Abstract:A new 3D-host-guest supramolecular coordination polymer (SCP); ∞3[(Cu3(CN)3)2.(DAHP)], 1 [1,7-diaminoheptane=.(DAHP)] had been synthesized by self-assembly at ambient conditions. X-ray single crystal diffraction of SCP 1 indicated the formation of two-fold [Cu3(CN)3]2 units containing tetrahedral copper(I) atoms which are arranged in unique way to create 3D-network. The neutral [Cu3(CN)3]2 building blocks create unique complex structure containing the minicycle [Cu2(μ3-CN)2] motif with wide cavities enable to … Show more
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