Effect of stabilizers in the thermal treatment of PVC—V. Effect of Ba and Cd butyrates, 2-ethylhexoates, laurates and stearates on the dehydrochlorination of PVC
“…This can be proved by the stabilizing efficiency of modified polyacrylic acids on the treated PVC reflected by reducing the extent of discoloration of induced by thermal treatment of PVC in comparison with blank PVC. This can be attributed to the dehydrohalogenation of PVC under thermal treatment conditions [16,18,19]. Figure 7 shows a lower extent of discoloration of the treated PVC samples relative to blank sample.…”
Section: Stabilizing Effect Of Modified Polyacrylic Acid On Pvcmentioning
Polyacrylic acid was converted into modified polymers with the targeted functional groups through the reaction with different organic compounds such as some aromatic amines and acids. The obtained modified polymeric products have been characterized through FT-IR spectroscopic and thermal analyses. Modified acrylic polymers were tested for their ability to be used for heavy metal ion recovery from their aqueous solutions. They also were tested as polymeric antioxidants for PVC as a standard polymer by using the discoloration extent of PVC as a function of thermal degradation of PVC due to the thermal treatment. The obtained results were discussed and justified.
“…This can be proved by the stabilizing efficiency of modified polyacrylic acids on the treated PVC reflected by reducing the extent of discoloration of induced by thermal treatment of PVC in comparison with blank PVC. This can be attributed to the dehydrohalogenation of PVC under thermal treatment conditions [16,18,19]. Figure 7 shows a lower extent of discoloration of the treated PVC samples relative to blank sample.…”
Section: Stabilizing Effect Of Modified Polyacrylic Acid On Pvcmentioning
Polyacrylic acid was converted into modified polymers with the targeted functional groups through the reaction with different organic compounds such as some aromatic amines and acids. The obtained modified polymeric products have been characterized through FT-IR spectroscopic and thermal analyses. Modified acrylic polymers were tested for their ability to be used for heavy metal ion recovery from their aqueous solutions. They also were tested as polymeric antioxidants for PVC as a standard polymer by using the discoloration extent of PVC as a function of thermal degradation of PVC due to the thermal treatment. The obtained results were discussed and justified.
“…The possibility of reaction with double bonds, which have already been formed or were available in the PVC chain, was not clearly indicated in the literature in the case of metal carboxylates, in contrast to the action of organotins 52 and phosphites, 23 which are believed to take part in the following reactions:…”
Section: Reactions With Isolated Unsaturationsmentioning
“…After good mechanical mixing of all components, sheets of thickness 1.0 mm were prepared by using a hot melt press (at T = 180 l 2 8C, pressure P = 8.0 tons and time t = 5.0 min). [8] In order to maintain a constant thickness, a frame of the desired thickness was used throughout all sheet preparations. The compositions and designations of the investigated PVC sheets are presented in Table 2.…”
Section: Preparation Of Stabilized and Plasticized Pvc Sheetsmentioning
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