Fatigue crack growth rate of line pipe steels in sour environments typically exhibits a steady-state value at low frequencies. However, in highly inhibited sour environments, there is no evidence of a steady-state fatigue crack growth at low frequencies. This is likely a result of static crack growth rate at K max . Stable static crack growth measured under constant stress intensity factor (K) conditions in inhibited sour environments was in the range of 10 −7 mm/s to 10 −8 mm/s. The crack growth rate in inhibited sour environments is likely associated with crack tip processes associated with metal dissolution/film formation and associated hydrogen evolution. The results obtained were modeled based on a crack tip strain rate based approach, where the rate limiting step was the metal dissolution/FeS formation and the corresponding hydrogen generation reaction.
CORROSIONJOURNAL.ORG100 150 200 250 300 350 400 450 500 K J 0.2 mm -Air K J maxload -Air K J 0.2 mm -Env K J maxload -Env K J (MPa√m) dK/dt (MPa√m/s) X65 parent pipe pH = 5 p H2S = 0.46 psia FIGURE 2. Effect of K-rate on the measured J 0.2 mm for API 5L X65 in sour environments on coated samples. 15 140 J 0.2 mm 5 wt% NaCl Uncoated pH 5, 1 psia H 2 S J maxload J 1 mm 120 100 80 60 40 20 0 0.01 0.1 K-Rate (N . mm -3/2 /s) J (N/mm) FIGURE 3. Effect of K-rate on the measured J 0.2 mm on API 5L X6 in sour environments on uncoated samples. 16