Effect of solvent on the physicochemical properties of electrospun nanocomposite with gamat oil and cerium oxide for potential medical engineering application
“…Using electrospinning, Narruddin et al fabricated and studied nanocomposites of polycaprolactone (PCL), containing different ratios of gamat oil and cerium oxide particles, that can be used in the healing of wounds. The obtained nanocomposites increased hydrophobicity, improved tensile strength and demonstrated physicochemical properties that are well suited for wound healing applications [ 86 ].…”
The development of advanced composite biomaterials combining the versatility and biodegradability of polymers and the unique characteristics of metal oxide nanoparticles unveils new horizons in emerging biomedical applications, including tissue regeneration, drug delivery and gene therapy, theranostics and medical imaging. Nanocrystalline cerium(IV) oxide, or nanoceria, stands out from a crowd of other metal oxides as being a truly unique material, showing great potential in biomedicine due to its low systemic toxicity and numerous beneficial effects on living systems. The combination of nanoceria with new generations of biomedical polymers, such as PolyHEMA (poly(2-hydroxyethyl methacrylate)-based hydrogels, electrospun nanofibrous polycaprolactone or natural-based chitosan or cellulose, helps to expand the prospective area of applications by facilitating their bioavailability and averting potential negative effects. This review describes recent advances in biomedical polymeric material practices, highlights up-to-the-minute cerium oxide nanoparticle applications, as well as polymer-nanoceria composites, and aims to address the question: how can nanoceria enhance the biomedical potential of modern polymeric materials?
“…Using electrospinning, Narruddin et al fabricated and studied nanocomposites of polycaprolactone (PCL), containing different ratios of gamat oil and cerium oxide particles, that can be used in the healing of wounds. The obtained nanocomposites increased hydrophobicity, improved tensile strength and demonstrated physicochemical properties that are well suited for wound healing applications [ 86 ].…”
The development of advanced composite biomaterials combining the versatility and biodegradability of polymers and the unique characteristics of metal oxide nanoparticles unveils new horizons in emerging biomedical applications, including tissue regeneration, drug delivery and gene therapy, theranostics and medical imaging. Nanocrystalline cerium(IV) oxide, or nanoceria, stands out from a crowd of other metal oxides as being a truly unique material, showing great potential in biomedicine due to its low systemic toxicity and numerous beneficial effects on living systems. The combination of nanoceria with new generations of biomedical polymers, such as PolyHEMA (poly(2-hydroxyethyl methacrylate)-based hydrogels, electrospun nanofibrous polycaprolactone or natural-based chitosan or cellulose, helps to expand the prospective area of applications by facilitating their bioavailability and averting potential negative effects. This review describes recent advances in biomedical polymeric material practices, highlights up-to-the-minute cerium oxide nanoparticle applications, as well as polymer-nanoceria composites, and aims to address the question: how can nanoceria enhance the biomedical potential of modern polymeric materials?
“…Consequently, the effect of DCM/ethanol on PEO/PHBV electrospun fibers in various ratios has been studied in detail. Nasruddin et al 111 investigated the spinnability of polycaprolactone (PCL)/cerium oxide with two different solvent systems. Morphological study of fiber diameter revealed a decrease.…”
Summary
Fuel cell technology has matured, and much emphasis has been placed on commercialization efforts for these systems, whether for stationary or portable applications. Several factors influence commercialization success, including the use of strong, durable, and cost‐effective material technology. The two most important components in a fuel cell are the catalyst and proton exchange membrane. In addition, some crucial characteristics need to be possessed: high catalytic activity, high surface area, high proton conductivity, low fuel permeability, and increased stability chemical, mechanical, and thermal. The following properties will require the development of catalysts and membranes in the nano‐scale structure. Nanofiber is a unique nanostructure that has been investigated in fuel cell technology to produce the catalyst and proton exchange membrane. The electrospinning technique has gained prominence to fabricate nanofibers because of its ease to use, simplicity, and wide range of applications. Thus, the main objective of this review is to provide an overview of the electrospinning process by explaining the operating principle, parameters influencing the electrospinning technique, and application of nanofibers in the fuel cell, specifically for the fabrication of electrolyte electrospun nanofiber membranes and fibrous materials as an electrochemical catalyst in fuel cell applications. This review also discusses the benefits of the investigated nanofiber materials and the challenges and prospects of the electrospinning technique in a fuel cell.
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