Effect of SO2 on the amine-based CO2 capture solvent and improvement using ion exchange resins

Gao, Jubao; Wang, Shujuan; Wang, Jian; Cao, Lingdi; Tang, Shiwei; Xiao, Yu

doi:10.1016/j.ijggc.2015.03.001

Cited by 22 publications

(13 citation statements)

References 35 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…On the basis of our previous work [35][36][37], this work develops an IL tailored amine aqueous absorbent for CO 2 capture in an IGCC process. The absorbents consist of 30 wt% N-methyldiethanolamine (MDEA), 3 wt% piperazine (PZ), 57 wt% H 2 O and 10 wt% RTIL with 1-butyl-3-methylimidazolium ([Bmim]) as the cation, and tetrafluoroborate ([BF 4 ]), nitrate ([NO 3 ]) or chloride ([Cl]) as the anions.…”

Section: Introductionmentioning

confidence: 99%

Ionic liquids tailored amine aqueous solution for pre-combustion CO2 capture: Role of imidazolium-based ionic liquids

et al. 2015

Self Cite

View full text Add to dashboard Cite

Section: Introductionmentioning

confidence: 99%

Ionic liquids tailored amine aqueous solution for pre-combustion CO2 capture: Role of imidazolium-based ionic liquids

et al. 2015

Self Cite

View full text Add to dashboard Cite

“…Therefore, the removal of HSS from the amine solvent is an indispensable part of gas sweetening industries. Various technologies that can be used to remove HSS ions from amine solvent include electrodialysis, thermal reclamation, ion exchange and distillation [ 19 , 20 , 21 , 22 ].…”

Section: Introductionmentioning

confidence: 99%

Modeling of Nanofiltration Process Using DSPM-DE Model for Purification of Amine Solution

et al. 2021

View full text Add to dashboard Cite

The formation of heat stable salts (HSS) during the natural gas sweetening process by amine solvent causes many problems such as corrosion, foaming, capacity reduction, and amine loss. A modeling study was carried out for the removal of HSS ions from amine solution using nanofiltration (NF) membrane process that ensures the reuse of amine solution for gas sweetening. This model studies the physics of the nanofiltration process by adjusting and investigating pore radius, the effects of membrane charge, and other membrane characteristics. In this paper, the performance of the ternary ions was investigated during the removal process from methyl di-ethanol amine solution by the nanofiltration membrane process. Correlation between feed concentration and permeate concentration, using experimental results with mathematical correlation as Ci,p = f (Ci,f) was used in modeling. The results showed that the calculated data from the model provided a good agreement with experimental results (R2 = 0.90–0.75). Also, the effect of operating conditions (including feed pressure and feed flow rate on ions rejection and recovery ratio across the flat-sheet membrane) was studied. The results showed that the recovery and rejection ratios of the NF membrane depend on the driving pressure across the membrane. While the driving pressure is affected by the feed flow conditions and feed pressure.

show abstract

“…Numerous studies have been conducted using ED to remove HSS from the amine solution. They found that ED is useful in removing anions and cations, but it can also cause absorbent losses during the process [ 21 ]. Bazhenov et al [ 22 ] studied the removal of HSS during the reclaiming of degraded monoethanolamine (MEA) solutions by ED in a pilot plant.…”

Section: Introductionmentioning

confidence: 99%

Application of NF Polymeric Membranes for Removal of Multicomponent Heat-Stable Salts (HSS) Ions from Methyl Diethanolamine (MDEA) Solutions

et al. 2020

View full text Add to dashboard Cite

This study presents an efficient and scalable process for removing the heat-stable salts (HSS) ions from amine solution while recovering methyl diethanolamine (MDEA) solution for its reuse in gas sweetening plants. The presence of HSS in the amine solution causes the loss of solvent capacity, foaming, fouling, and corrosion in gas sweetening units so their removal is crucial for a more well-performing process. Furthermore, the recovery of the amine solution can make the sweetening step a more sustainable process. In this study, for the first time, the removal of a multicomponent mixture of HSS from MDEA solution was investigated via a nanofiltration process using flat-sheet NF-3 membranes. The impact of operating parameters on salts and amine rejection, and flux, including the operating pressure, HSS ions concentration, and MDEA concentration in the feed solution was investigated. Results based on the nanofiltration of an amine stream with the same composition (45 wt.% MDEA solution) as that circulating in a local gas refinery (Ilam Gas refinery), demonstrated a removal efficiency of HSS ions in the range from 75 to 80% and a MDEA rejection of 0% indicating the possibility of reusing this stream in the new step of gas sweetening.

show abstract

Effect of SO2 on the amine-based CO2 capture solvent and improvement using ion exchange resins

Cited by 22 publications

References 35 publications

Ionic liquids tailored amine aqueous solution for pre-combustion CO2 capture: Role of imidazolium-based ionic liquids

Ionic liquids tailored amine aqueous solution for pre-combustion CO2 capture: Role of imidazolium-based ionic liquids

Modeling of Nanofiltration Process Using DSPM-DE Model for Purification of Amine Solution

Application of NF Polymeric Membranes for Removal of Multicomponent Heat-Stable Salts (HSS) Ions from Methyl Diethanolamine (MDEA) Solutions

Contact Info

Product

Resources

About