2013
DOI: 10.1016/j.micromeso.2013.02.021
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Effect of Si/Al ratio on mesopore formation for zeolite beta via NaOH treatment and the catalytic performance in α-pinene isomerization and benzoylation of naphthalene

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Cited by 76 publications
(49 citation statements)
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“…In general, the acid property was determined by the Si/Al ratios of the zeolites [35], and the results agreed well with the IEC test. The acid sites were mainly introduced by the Al in the framework and extra-framework from the zeolite.…”
Section: The Reusability Study and Leaching Testsupporting
confidence: 69%
“…In general, the acid property was determined by the Si/Al ratios of the zeolites [35], and the results agreed well with the IEC test. The acid sites were mainly introduced by the Al in the framework and extra-framework from the zeolite.…”
Section: The Reusability Study and Leaching Testsupporting
confidence: 69%
“…5 and the quantitative result is listed out in Table 2. For HZSM-5, the two distinct desorption peaks of NH 3 appeared at about 190 and 390°C, indicating that HZSM-5 presents weak and medium strong acidic sites simultaneously [25][26][27][28]. With the Ni loadings of 0.76-5.05 wt.% were implemented, the peak position and area of weak acidic sites kept almost unchanged, while the peak of medium strong area gradually decreased, indicating the continuous reduction of medium strong acid sites on the Ni/HZSM-5 surfaces.…”
Section: Acidic Propertiesmentioning
confidence: 99%
“…As shown in Fig. S3, there are two ammonia desorption peaks for all catalysts, which correspond to two different types of acid site [21,22]. After the deconvolution and ammonia quantification [23], each profile can be deconvoluted by the Gauss curve fitting method into two separated peaks, where the amounts of weak and strong acid sites can be calculated and summarized in Fig.…”
Section: Catalyst Characterizationmentioning
confidence: 99%