1987
DOI: 10.1346/ccmn.1987.0350308
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Effect of Saturating Cation, pH, and Aluminum and Iron Oxide on the Flocculation of Kaolinite and Montmorillonite

Abstract: Abstract--The effect of pH on the flocculation-dispersion behavior of noncrystalline aluminum and iron oxides, kaolinite, montmorillonite, and various mixtures of these materials was investigated. The clays were Na-or Ca-saturated and freeze-dried before use. Critical coagulation concentrations (CCC) of all materials and mixtures were found to be pH dependent. The A1 oxide was flocculated at pH >9.5 and the iron oxide was flocculated between pH 6.0 and 8.2; i.e., flocculation occurred at pHs near the point of … Show more

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Cited by 175 publications
(89 citation statements)
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References 26 publications
(31 reference statements)
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“…Several authors (Igwe et al 1999;Lado et al 2004) found no positive correlations between SOM and aggregate stability. It means that SOM is the only factor responsible for aggregation processes and the mechanisms of the aggregate forming can be based on other principles, for example the bonding between mineral elements and sesquioxides, or on physical and chemical properties of clay minerals (Goldberg & Glaubig 1987;KÖgel-Knabner et al 2008). In the case of Cambisols, the highest contents of WSA ma could be due to the bond between SOM and mineral elements.…”
Section: Resultsmentioning
confidence: 99%
“…Several authors (Igwe et al 1999;Lado et al 2004) found no positive correlations between SOM and aggregate stability. It means that SOM is the only factor responsible for aggregation processes and the mechanisms of the aggregate forming can be based on other principles, for example the bonding between mineral elements and sesquioxides, or on physical and chemical properties of clay minerals (Goldberg & Glaubig 1987;KÖgel-Knabner et al 2008). In the case of Cambisols, the highest contents of WSA ma could be due to the bond between SOM and mineral elements.…”
Section: Resultsmentioning
confidence: 99%
“…To analyze factors which influence the dispersion and flocculation behavior of soil particles, many studies have so far been conducted. The factors considered to be important include organic matter (Visser and Caillier 1988;Piccolo and Mbagwu 1989), free oxides (Oades 1984;Goldberg 1989), electric charge of clays (Pilipovich et al 1958;Black and Sidney 1961), clay mineralogy (VelascoMolina et al 1971), exchangeable cation composition (Chiet al 1977;Emerson and Chi 1977), electrolyte concentration (Quirk and Schofield 1955), soil pH (Goldberg and Glaubig 1987), particle size distribution (Rengasamy et al 1984) and so on. However, since the characteristics of the soil samples investigated in these studies were different from place to place, care must be taken in the interpretation of the role of the factors.…”
Section: Discussionmentioning
confidence: 99%
“…In addition, because pH affects soil charge, it strongly influences the dispersion-flocculation of soils. Flocculation occurred near the point of zero charge; the aluminum (Al) oxide was flocculated at pH > 9.5 and the iron oxide was flocculated between pH 6.0 and 8.2 (Goldberg and Glaubig 1987). The soil dispersed well and the permeability decreased well at pH 9 more than those at pH 6 for the montmorillonitic and the kaolinitic soil (Suarez et al 1984).…”
Section: Introductionmentioning
confidence: 99%