Porous
polyimide (PI) materials are one of important bearing retainer
materials in space applications due to the storage and continuous
supply of a lubricant through the porous structure. Understanding
the lubricant recycling process in porous polyimide retainers is of
vital importance to improve lubricant supply performance of bearing.
In this work, through molecular dynamic simulations, coarse-grained
models are built to study lubricant recycling processes on porous
and solid surfaces. A spontaneous imbibition behavior is observed
when the lubricant is present on the porous surface. The dynamic change
in the contact angle in this process and the deviation of the effective
radius from the volumetric radius because of the molecular structure
of polyimide causes the classical Lucas–Washburn (L–W)
equation fail to describe the process. By fitting dynamic contact
angle and effective radius, a modified L–W equation is developed,
which well predicts the process of imbibition. Furthermore, it is
found that the lubricants between the porous polyimide surface and
the solid surface are recycled by extrusion, and spontaneous imbibition
does not occur. In this case, the accumulation of lubricant pressure
and weak interfacial interaction between the lubricant and the solid
surface are also the main factors that promote lubricant recycling.