1995
DOI: 10.1111/j.1708-8240.1995.tb00730.x
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Effect of pH on Hydrogen Peroxide Bleaching Agents

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Cited by 57 publications
(42 citation statements)
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“…It has been reported that HP delivered in an alkaline medium increases the bleaching effectiveness. 22 For instance, in a pH of 9, the dissociation rate of the HP was shown to be 2.7 times higher than in an acidic solution 22 (pH=4.4), most probably due to the fact that the dissociation constant (pKa) of the HP is around 11.5.…”
Section: Discussionmentioning
confidence: 99%
“…It has been reported that HP delivered in an alkaline medium increases the bleaching effectiveness. 22 For instance, in a pH of 9, the dissociation rate of the HP was shown to be 2.7 times higher than in an acidic solution 22 (pH=4.4), most probably due to the fact that the dissociation constant (pKa) of the HP is around 11.5.…”
Section: Discussionmentioning
confidence: 99%
“…8,13 Because of the absence of an electron on the last layer, the oxygen (O ) -free radicals -are extremely electrophilic and diffuse throughout enamel and dentin matrix to attack the macromolecules of pigments (organic molecules) and acquire stability. 7,8 Then, the intrinsic pigments composed by highly unsaturated organic macromolecules are transformed into less complex molecules, which are smaller, simpler and lighter than the original ones. 8 However, this reaction is unspecific, and the organic and inorganic matrix of the enamel and dentin might be affected by the bleaching agents, and undesirable effects such as topography alterations and mineral loss may occur.…”
Section: Introductionmentioning
confidence: 99%
“…11,12 Because of their electron-deficient state, these free radicals diffuse into organic matrix of the pigments by penetrating the enamel and dentin and become stable. 11,13 After this, there is transformation of unsaturated organic molecules into smaller components and it is a very nonspecific reaction and the bleaching agents alter the components of enamel and dentin and structural changes occur in them.…”
Section: 5005/jp-journals-10024-1837mentioning
confidence: 99%