A high concentration of dissolved gaseous mercury (DGM) was detected in post-desulfurized waste seawater, which was discharged from a coal-fired power plant equipped with a seawater desulfurization system and which was located in a coastal area. A large amount of DGM was converted from other forms of mercury during transformation processes, such as photo-reduction. The present study targeted the photo-reduction of mercury and the effects of various environmental parameters on DGM production in the post-desulfurized seawater discharged. The results suggested that the photoreduction of mercury was significantly induced under UV radiation, especially with UVB. The particulate mercury on suspended solids was easily photo-reduced and considered as an important source of DGM. It was confirmed that the suspended solids in postdesulfurized seawater could enhance the reduction process of mercury under UV radiation. The pseudo-firstorder rate constants of DGM production, which were determined through the concentration gradient and trial methods, were 1.39×10 −3 min −1 and 1.45×10 −3 min −1 , respectively. The values showed no significant difference and were both much higher than the reported results, indicating that the photo-reduction of mercury in post-desulfurized seawater deserved more attention. In addition, the initial mercury level was observed when mixing the post-desulfurized seawater with fresh seawater, and this suggested that a significant amount of initial mercury would be produced when the post-desulfurized seawater was discharged into the adjacent sea area and thus becomes another considerable source of DGM.